40168-13-6

Upstream product

• 134-32-7 1-amino-naphthalene 
• 603-35-0 triphenylphosphine 
• 60-29-7 diethyl ether 
• 6921-40-0 1-azidonaphthalene 

Downstream Products

• 551-06-4 1-isothiocyanatonaphthalene 
• 3878-45-3 triphenylphosphine sulfide 
• 86-84-0 1-Naphthyl isocyanate 
• 791-28-6 Triphenylphosphine oxide 
• 1259404-97-1 [Pd(μ-Cl)(C6H4-(PPh2=N-C10H7-1)-2)-κ-C,N]2 
• 93619-63-7 N-(4-Methyl-benzyl)-N'-naphthalen-1-yl-N''-(2-oxo-4,6-diphenyl-2H-pyridin-1-yl)-guanidine 
• 77221-09-1 5,7-diphenyl-1,3,4-oxadiazolo<3,2-a>pyridilium-2-(α-naphthylaminide) 

Relevant academic research and scientific papers

Reaction between triphenylphosphine and aromatic amines in the presence of diethyl azodicarboxylate: An efficient synthesis of aryliminophosphoranes under neutral and mild conditions

An efficient synthesis of aryliminophosphoranes is described. A mixture of an aromatic amine, diethyl azodicarboxylate and triphenylphosphine undergo a Mitsonobu type reaction at ambient temperature in dry dichloromethane to afford aryliminophosphoranes in excellent yields.

Copper(II) acetate/oxygen-mediated nucleophilic addition and intramolecular C-H activation/C-N or C-C bond formation: One-pot synthesis of benzimidazoles or quinazolines

Diarylcarbodiimides or benzylphenylcarbodiimides are converted to 1,2-disubstituted benzimidazoles or 1,2-disustituted quinazolines via addition/intramolecular C-H bond activation/C-N or C-C bond forming reaction using copper(II) acetate/oxygen [Cu(OAc)2/O2] as the oxidant at 100°C in one-pot cascade procedure. Copyright

Vinyltriphenylphosphonium salt mediated serendipitous synthesis of aryliminophosphoranes

Crystalline phosphorus ylides are obtained in excellent yields from the 1:1:1 addition reaction between triphenylphosphine, dimethyl acetylenedicarboxylate and aromatic amines, such as aniline, 1-naphthylamine, p-toluidine, 4-bromoaniline, 4-nitroaniline, 4-acetylaniline, 2-aminopyridine, or 2-amino-5-bromopyridine. These stabilized phosphoranes undergo a smooth intramolecular reaction in boiling p-xylene or toluene to produce aryliminophosphoranes in excellent yields.

Iminophosphorane-substituted Proton Sponges. Part 2. Preparation and Crystal Structure of Four Phosphoranylideneammonionaphthalene Derivatives

Crystal structure analysis of salts of one monosubstituted (1) and three peri disubstituted naphthalene derivatives (2, 3 and 4) are described.The strong repulsion between the nitrogen lone pairs in neutral structures is replaced by an intramolecular N(1+