4017-83-8

Basic information

• Product Name: (-)-(1R,3R,6S)-4-methylene-7,7-dimethylbicyclo[4.1.0]heptan-3-ol
• Synonyms: (-)-(1R,3R,6S)-4-methylene-7,7-dimethylbicyclo[4.1.0]heptan-3-ol
• CAS NO: 4017-83-8
• Molecular Weight: 152.236
• Mol File: 4017-83-8.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: (-)-(1R,3R,6S)-4-methylene-7,7-dimethylbicyclo[4.1.0]heptan-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-(1R,3R,6S)-4-methylene-7,7-dimethylbicyclo[4.1.0]heptan-3-ol(4017-83-8)
• EPA Substance Registry System: (-)-(1R,3R,6S)-4-methylene-7,7-dimethylbicyclo[4.1.0]heptan-3-ol(4017-83-8)

Safety Data

• Hazardous Substances Data: 4017-83-8(Hazardous Substances Data)

Upstream product

• 116872-39-0 (+/-)-10-phenylsulfonylcar-3-ene 
• 10309-63-4 (-)-Caran-3β,4β-diol-4-acetat 
• 22556-08-7 trans-3,4-caranediol 
• 498-15-7 (+)-Δ³-carene 
• 10309-65-6 (-)-4α-acetoxy-3β-hydroxy-trans-carane 
• 936-91-4 3-carene epoxide 
• 4017-86-1 4-Nitro-benzoat von (-)-(1S:4R:6R)-4-Hydroxy-Δ³⁽¹⁰⁾-carven 
• 10309-64-5 (-)-(1R,3R,6S)-4-methylene-7,7-dimethylbicyclo<4.1.0>heptan-3-ol acetate 

Downstream Products

• 1330616-27-7 (1S,3R,4R,6R)-7,7-dimethyl-3-(((S)-1-phenylethylamino)methyl)bicyclo[4.1.0]heptane-3,4-diol 
• 1330616-26-6 (1S,3R,4R,6R)-7,7-dimethyl-3-(((R)-1-phenylethylamino)methyl)bicyclo[4.1.0]heptane-3,4-diol 
• 1330616-23-3 (1S,3R,4R,6R)-3-(benzyl((S)-1-phenylethyl)amino)methyl-7,7-dimethylbicyclo[4.1.0]heptane-3,4-diol 
• 1330616-21-1 (1S,3R,4R,6R)-3-(benzyl((R)-1-phenylethyl)amino)methyl-7,7-dimethylbicyclo[4.1.0]heptane-3,4-diol 
• 1330616-20-0 (1S,3R,4R,6R)-3-(benzylamino)methyl-7,7-dimethylbicyclo[4.1.0]heptane-3,4-diol 
• 1330616-18-6 (1S,3R,4R,6R)-3-(dibenzylamino)methyl-7,7-dimethylbicyclo[4.1.0]heptane-3,4-diol 
• 1330616-17-5 (1S,3R,4R,6R)-3-(benzyl(methyl)amino)methyl-7,7-dimethylbicyclo[4.1.0]heptane-3,4-diol 
• 1330616-51-7 (1aR,2aR,6aR,7aS)-6a-hydroxy-1,1-dimethyl-5-((S)-1-phenylethyl)decahydro-3-oxa-5-azacyclopropa[g]naphthalene 
• 1330616-49-3 (1aR,2aR,6aR,7aS)-6a-hydroxy-1,1-dimethyl-5-((R)-1-phenylethyl)decahydro-3-oxa-5-azacyclopropa[g]naphthalene 
• 1330616-41-5 (1aR,2aR,6aR,7aS)-5-benzyl-1,1-dimethyl-6a-hydroxydecahydro-3-oxa-5-azacyclopropa[g]naphthalene 
• 4176-04-9 (1R,4S,6S)-4,7,7-Trimethyl-bicyclo[4.1.0]heptan-3-one 
• 4176-01-6 (-)-isocaranone 
• 4176-02-7 (-)-cis-Caran-3-on-semicarbazon 
• 4175-95-5 (-)-4-Caranon-semicarbazon 

Relevant articles and documents

Stereoselective Synthesis of Carane-Type Hydroxythiols and Disulfides Based on Them

Isomeric 10-sulfanylcaran-4-ols and 4-sulfanylcaran-3-ols were synthesized and used to prepare disulfides in high yields.

Synthesis of chiral thienylpyridines from naturally occurring monoterpenes: Useful ligands for cyclometallated complexes

On treatment with ammonium acetate, α,β-unsaturated ketones or aldehydes can easily undergo condensation with acetylpyridinium salts (Krohnke reaction). Four 'thienylpyridine' ligands, derived from (-)-β-pinene, (+)-camphor, (+)-3-carene and (+)-2-carene, were prepared according to this method. The multistep syntheses to get (1R,5R)-3-methylenenopinone (5), (+)-3-methylenecamphor (10), (-)-3-caren-10-al (15) and (1S,6R)-7,7-dimethyl-3-methylenebicyclo[4.1.0]heptan-2-one (18) are also described.

2-PHENYLSULFINYLMETHYL-1,3-BUTADIENE IN THE THERMAL DIELS-ALDER REACTION

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