40193-89-3Relevant academic research and scientific papers
FRAGMENTATION OF PHOSPHORANES: THE REACTION OF Δ3-PHOSPHOLENES WITH PHENANTHRAQUINONE
Hammond, Philip J.,Lloyd, John R.,Hall, C. Dennis
, p. 47 - 52 (2007/10/02)
Stereochemically pure cis- and trans-Δ3-phospholenes react with phenanthraquinone to form pentaco-ordinate adducts which, when heated, fragment to trans,-trans-hexa-2,4-diene and phosphonite.The relative rates of fragmentation of the adducts from 1-methyl and 1-aryl phospholenes are reported and discussed.
