40231-69-4Relevant academic research and scientific papers
Stereoelectronic effect in the capture reaction of the 1,2-dimesityl-2-phenylvinyl radical
Chen, Xin,Yamataka, Hiroshi,Galli, Carlo,Rappoport, Zvi
, p. 1369 - 1373 (2007/10/03)
The reduction of (E)-1,2-dimesityl-2-phenylvinyl bromide (E-4-Br) to the corresponding ethene (4-H) under radical conditions (Bu3SnH-AIBN-benzene-hv) proceeds with predominant inversion of configuration to give an E-4-H/Z-4-H ratio of ≥9:1. Thi
