40244-26-6Relevant academic research and scientific papers
A novel reduction reaction for the conversion of aldehydes, ketones and primary, secondary and tertiary alcohols into their corresponding alkanes
Nimmagadda, Rama D.,McRae, Christopher
, p. 5755 - 5758 (2007/10/03)
A novel one-pot reaction has been developed for the reduction of aldehydes, ketones and primary, secondary and tertiary alcohols into their corresponding alkyl function. This is also the first reported method which can efficiently reduce primary, secondary, or tertiary alcohols, without affecting carbon-carbon double bonds, into their corresponding alkyl function in high yields. The reduction utilises either diethylsilane or n-butylsilane as the reducing agent in the presence of the Lewis acid catalyst tris(pentafluorophenyl)borane.
NICKEL BORIDE REDUCTIVE CLEAVAGE OF ALLYLIC TRIMETHYLSILYL ETHERS
Sarma, D. N.,Sharma, R. P.
, p. 371 - 372 (2007/10/02)
Nickel boride reductive cleavage of allylic trimethylsilyl ethers yielding alkenes is described.
Pd(0)-Catalyzed Electroreductive Cleavage of Allylic Acetates1
Torii, Sigeru,Tanaka, Hideo,Katoh, Tetsuo,Morisaki, Kazuo
, p. 3207 - 3208 (2007/10/02)
Pd(0)-catalyzed electroreductive cleavage of allylic acetates yielding alkenes and/or allyltrimethylsilanes is described.Deprotection of allyl esters can be performed in the same electrolysis system.
Reductive displacement of allylic acetates by hydride transfer via catalytic activation by palladium(0) complexes
Hutchins, Robert O.,Learn, Keith,Fulton, Robert P.
, p. 27 - 30 (2007/10/02)
Allylic acetates are reduced to alkenes by reductive displacement by hydride reagents via catalytic activation with Pd(0) complexes. In the absence of hydrides, allylic acetates afford conjugated dienes in DMSO solvent.
