402491-18-3Relevant academic research and scientific papers
Directed and undirected asymmetric dihydroxylation reactions: Application in the synthesis of a C-linked analogue of allolactose
Hodgson,Mahid,Nelson
, p. 2076 - 2077 (2001)
The complex OsO4·(S,S)-1,2-diphenyl-N,N′-bis(2,4,6- trimethylbenzyl) ethane-1,2-diamine is an effective reagent for the desymmetrisation of meso-1,2-bis(3,6-dihydro-2H-pyran-2-yl)ethanes by asymmetric dihydroxylation; this process, whose sense of diastereoselectivity depends on substitution and stereochemistry, has been exploited in the synthesis of a C-linked analogue of allolactose.
Desymmetrisation of meso difuryl alcohols, diols and their derivatives: Complementary directed and undirected asymmetric dihydroxylation reactions
Hodgson, Robert,Majid, Tahir,Nelson, Adam
, p. 1631 - 1643 (2007/10/03)
Asymmetric reactions (for example, asymmetric epoxidation and asymmetric dihydroxylation) were examined for the desymmetrisation of the meso substrates 1,1-difuran-2-ylmethanol,N-(1,1-difuran-2-ylmethyl)-4- methylbenzenesulfonamide, (R,S)-1,4-difuran-2-yl
