402857-96-9Relevant academic research and scientific papers
Construction of spiro[4.5]decane via ring-closing metathesis reaction: Formal synthesis of acorone and isoacorones
Srikrishna,Rao, M. Srinivasa
experimental part, p. 1423 - 1429 (2009/04/07)
A Claisen rearrangement and RCM reaction based sequence has been developed for formal total synthesis of acorone and isoacorones starting from cyclohexane-1,4-dione. It has been further modified and avoided the protection-deprotection sequence in the second strategy.
A ring closing metathesis based approach for the spiroannulation of cyclopentanes and cyclohexanes. Formal synthesis of (±)-acorones
Srikrishna,Rao,Gharpure,Babu
, p. 1986 - 1988 (2007/10/03)
An efficient ring closing metathesis (RCM) reaction based approach was developed for the spiroannulation of cyclopentanes and cyclohexanes and its utility demonstrated in the formal synthesis of the spirosesquiterpenes acorones.
