402933-87-3

Upstream product

• 545-06-2 trichloroacetonitrile 
• 402933-91-9 allyl 3,4,6-tri-O-benzyl-2-O-(9-fluorenylmethoxycarbonyl)-α-D-mannopyranoside 

Downstream Products

• 514792-72-4 C₁₁₁H₁₁₀N₂O₂₄ 
• 171243-37-1 C₃₅H₃₈O₇ 
• 171243-38-2 C₆₂H₆₆O₁₂ 
• 171243-62-2 C₈₉H₉₄O₁₇ 

Relevant academic research and scientific papers

One-pot catalytic glycosidation/Fmoc removal - An iterable sequence for straightforward assembly of oligosaccharides related to HIV gp120

The removal of a transient Fmoc protecting group can be simply performed by the addition of excess Et3N just after the accomplishment of a Bi(OTf)3-promoted glycosidation reaction. The obtained oligosaccharide can be directly employed as a glycosyl acceptor for further elongation of the saccharide. The preparation of biologically important, linear and branched mannans incorporated into HIV gp 120 demonstrates that the iteration of this one-pot sequence leads to a very straightforward oligosaccharide assembly.

Solid-phase oligosaccharide synthesis of a small library of N-glycans

Solid-phase oligosaccharide synthesis is based on a hydroxymethyl-benzyl benzoate spacer linker which is connected to the Merrifield resin (1P). Glycosylation was performed with O-glycosyl trichloroacetimidates of glucosamine, mannose, and galactose permi

Solid phase syntheses of oligomannosides and of a lactosamine containing milk trisaccharide using a benzoate linker

Galactose and mannose building blocks 9 and 12 were designed for the solid phase synthesis of oligosaccharides (SPOS). Both compounds were employed after condensation with benzoic acid function containing resin 10 in SPOS of human milk trisaccharide 1 and