40296-03-5

Basic information

• Product Name: Benzenamine, N-(1-methylpropylidene)-
• CAS NO: 40296-03-5
• Molecular Formula: C10H13N
• Molecular Weight: 147.22
• Mol File: 40296-03-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-(1-methylpropylidene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-(1-methylpropylidene)-(40296-03-5)
• EPA Substance Registry System: Benzenamine, N-(1-methylpropylidene)-(40296-03-5)

Safety Data

• Hazardous Substances Data: 40296-03-5(Hazardous Substances Data)

Upstream product

• 85599-85-5 2-methyl-2-(phenylamino)pentane nitrile 
• 62-53-3 aniline 
• 78-93-3 butanone 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 33966-50-6 SEC-BUTYLAMINE 

Downstream Products

• 881008-34-0 N-sec-butyl-aniline 
• 74478-33-4 1,2-diethyl-1,2-dimethyl-N,N'-diphenyl-ethanediyldiamine 
• 75251-04-6 N-Lithio-N-(1-methylenpropyl)benzolamin 
• 75251-01-3 (E)-N-Lithio-N-(1-methyl-1-propenyl)benzolamin 
• 85599-85-5 2-methyl-2-(phenylamino)pentane nitrile 
• 14465-46-4 N-(3-methylpent-1-yn-3-yl)aniline 
• 75251-17-1 N-(1-Methylenpropyl)benzolamin 
• 24235-20-9 (E)-N-(1-Methyl-1-propenyl)benzolamin 
• 261505-53-7 4-hydroxy-7,8-dimethyl-6-phenyl-pyrano[3,2-c]pyridine-2,5(6H)-dione 
• 81023-46-3 N-<3-Phenylimino-2-(phenyliminomethyl)-1-pentenyl>benzolamin 
• 81023-46-3 C₂₄H₂₃N₃ 
• 81187-30-6 N-(2-Methyl-3-phenylimino-1-butenyl)benzolamin 

Relevant articles and documents

High-Throughput Mass Spectrometry Screening Platform for Discovering New Chemical Reactions under Uncatalyzed, Solvent-Free Experimental Conditions

A gas-phase high-throughput reaction screening platform was developed for the first time to study chemical structures of closely related functional groups and for the discovery of novel organic reaction pathways. Experiments were performed using the contained atmospheric pressure chemical ionization (APCI) source that enabled nonthermal, nonequilibrium plasma chemistry to be monitored by mass spectrometry (MS) in real time. This contained-APCI MS platform allowed an array of reagents to be tested, resulting in the studies of multiple gas-phase reactions in parallel. By exposing headspace vapor of the selected reagents to corona discharge, solvent-free Borsche-Drecsel cyclization reaction, Katritzky chemistry, and Paal-Knorr pyrrole synthesis were examined in the gas phase, outside the high vacuum environment of the mass spectrometer. A new radical-mediated hydrazine coupling reaction was also discovered, which provided a selective pathway to synthesize secondary amines without using a catalyst. The mechanisms of these atmospheric pressure gas-phase reactions were explored through the direct capture of intermediates and via comparison with the corresponding bulk solution and droplet-phase reactions.

Cobalt-Catalyzed Synthesis of Aromatic, Aliphatic, and Cyclic Secondary Amines via a "hydrogen-Borrowing" Strategy

The replacement of precious metals with inexpensive, less toxic, and earth-abundant elements in typical noble-metal-mediated organic transformations is a major goal in current synthetic chemistry and industries. The metal-catalyzed N-alkylation of amines with other amines through a "hydrogen-borrowing" principle represents a green and atom-economical reaction for the synthesis of secondary amines. However, catalysts developed thus far that are effective for this process remain quite scarce and are only limited to a few ruthenium and iridium complexes. In this work, we present a cobalt-catalyzed selective alkylation of amines with amines to synthesize a large variety of secondary amines. A range of amine substrates have been converted to the corresponding products through hetero- or homocoupling between amines. Cyclic sec-amines are also achieved from diamine precursors as rare examples.

N-Silylenamine durch Silylierung von Iminen mit Trimethylsilyl-triflat

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