40349-76-6

Upstream product

• 3695-77-0 triphenylmethanethiol 

Downstream Products

• 75938-83-9 4-(triphenylmethylthio)azetidin-2-one 
• 87791-40-0 (3S,4R)-3-bromo-4-triphenylmethylthio-2-azetidinone 
• 75940-38-4 Chloro-(2-oxo-4-tritylsulfanyl-azetidin-1-yl)-acetic acid 2-trimethylsilanyl-ethyl ester 
• 75940-37-3 Hydroxy-(2-oxo-4-tritylsulfanyl-azetidin-1-yl)-acetic acid 2-trimethylsilanyl-ethyl ester 
• 82318-31-8 Hydroxy-(2-oxo-4-tritylsulfanyl-azetidin-1-yl)-acetic acid 4-nitro-benzyl ester 
• 75938-86-2 Chloro-(2-oxo-4-tritylsulfanyl-azetidin-1-yl)-acetic acid 4-nitro-benzyl ester 
• 75940-39-5 (2-Oxo-4-tritylsulfanyl-azetidin-1-yl)-(triphenyl-λ⁵-phosphanylidene)-acetic acid 2-trimethylsilanyl-ethyl ester 
• 75938-87-3 (2-Oxo-4-tritylsulfanyl-azetidin-1-yl)-(triphenyl-λ⁵-phosphanylidene)-acetic acid 4-nitro-benzyl ester 
• 87791-41-1 (4R)-trithylthio-2-azetidinone 
• 102840-69-7 triphenylmethylthiolatocopper(I) 
• 807614-26-2 [Cu(2-methylthio-N-(2-pyridylmethyl)acetamide(-1H))(triphenylmethylmercaptan(-1H))] 

Relevant academic research and scientific papers

Synthesis and reactivity of thiolate-bridged multi-iron complexes supported by cyclic (alkyl)(amino)carbene

The combined utilization of Me2-cAAC (Me2-cAAC =:C(CH2)(CMe2)2N-2,6-iPr2C6H3) and thiolates as supporting ligands enables the access of unprecedented carbene coordinated thiolate-bridged diiron(ii) complexes [(Me2-cAAC)Fe(μ-SR)(Br)]2 (R = Me, 3; R = Et, 4). The coordination environment of each tetrahedral iron(ii) center in complexes 3 and 4 is composed of one terminal bromide atom, one carbene carbon atom and two thiolate sulfur atoms, which is similar to the carbide-containing sulfur-rich environment of iron centers in the belt region of the FeMo-cofactor. Interestingly, when NaSCPh3 was chosen as the thiolate ligand, C-S bond homolysis occurred to form a rare [3:1] site-differentiated cubane-type cluster [(Me2-cAAC)Fe4S4(Br)3][Me2-cAACH] (5). Furthermore, complexes 3 and 4 exhibit good exchange reactivity toward the azide anion to give novel thiolate-bridged diiron complexes with two azido ligands in a trans arrangement.