403609-50-7

Basic information

• Product Name: [1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) 3,6-dichloro-1,2-benzenedithiolate
• Synonyms: [1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) 3,6-dichloro-1,2-benzenedithiolate
• CAS NO: 403609-50-7
• Molecular Weight: 733.862
• Mol File: 403609-50-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) 3,6-dichloro-1,2-benzenedithiolate(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) 3,6-dichloro-1,2-benzenedithiolate(403609-50-7)
• EPA Substance Registry System: [1,1'-bis(diisopropylphosphino)ferrocene]palladium(II) 3,6-dichloro-1,2-benzenedithiolate(403609-50-7)

Safety Data

• Hazardous Substances Data: 403609-50-7(Hazardous Substances Data)

Upstream product

• 87314-49-6 3,6-dichlorobenzene-1,2-dithiol 
• 215788-65-1 dichloro[ferrocene-1,1'-diylbis(diisopropylphosphine-P)]palladium(II) 

Relevant articles and documents

Bidentate aryldichalcogenide complexes of [(diphosphino)ferrocene]palladium(II) and [(diphosphino)ferrocene]platinum(II). Synthesis, molecular structures and electrochemistry

A series of homochalcogenide and mixed-chalcogenide ligand complexes of palladium and platinum have been prepared from the reactions of Pd(dppf)Cl2, (dppf = 1,1′-bis(diphenylphosphino)ferrocene), Pd(dippf)Cl2 (1,1′-bis(diisopropylphosphino)ferrocene), and Pt(dppf)Cl2 with 1,2-benzenedithiol (HSC6H4SH) (a), 3,4-toluenedithiol (HSC6H3MeSH) (b), 3,6-dichloro-1,2-benzenedithiol (HSC6H2Cl2SH) (c), 2-mercaptophenol (HSC6H4OH) (d), thiosalicylic acid (HSC6H4CO2H) (e) and thionicotinic acid (HSC6H3NCO2H) (f). Single-crystal X-ray diffraction studies show that all complexes have distorted square-planar geometry. The complexes undergo two quasi-reversible or irreversible one-electron redox processes that involve the chalcogen ligands and diphosphinoferrocene ligands. The oxidation potentials of the chalcogen ligands increase when they bear electron-withdrawing substituents.