40364-80-5Relevant articles and documents
An efficient method for the cleavage of p-methoxybenzylidene (PMP), tetrahydropyranyl (THP) and 1,3-dithiane protecting groups by Selectfluor
Liu, Junjie,Wong, Chi-Huey
, p. 4037 - 4039 (2007/10/03)
A new and efficient method for the cleavage of the PMP, THP and 1,3-dithiane protecting groups with Selectfluor has been developed.
A 13C AND 1H NMR STUDY OF FORMALDEHYDE REACTIONS WITH ACETALDEHYDE AND ACROLEIN. SYNTHESIS OF 2-(HYDROXYMETHYL)-1,3-PROPANEDIOL
Nielsen, Arnold T.,Moore, Donald W.,Schuetze, Bryan D.
, p. 1393 - 1403 (2007/10/02)
The 13C i 1H NMR spectra of various formaldehyde-acetaldehyde and formaldehyde-acrolein mixtures in buffered aqueous solutions were examined.Reaction intermediates and products were assayed including 3-hydroxypropanal, 3-hydroxy-2-(hydroxymethyl)propanal, pentaerythrose and pentaerythritol.Reaction mixtures were hydrogenated under various conditions to yield mixtures of 1,3-propanediol, pentaerythritol and 2-(hydroxymethyl)-1,3-propanediol.The latter compound was also prepared by an efficient new procedure from 3,3-diethoxy-2-(hydroxymethyl)-1-propanol.