40365-64-8

Basic information

• Product Name: HEXA-4,5-DIEN-1-OL
• Synonyms: HEXA-4,5-DIEN-1-OL;4,5-Hexadien-1-ol
• CAS NO: 40365-64-8
• Molecular Formula: C₆H₁₀O
• Molecular Weight: 98.14
• Mol File: 40365-64-8.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 166.783°C at 760 mmHg
• Flash Point: 71.59°C
• Appearance: /
• Density: 0.826g/cm³
• Vapor Pressure: 0.581mmHg at 25°C
• Refractive Index: 1.436
• CAS DataBase Reference: HEXA-4,5-DIEN-1-OL(CAS DataBase Reference)
• NIST Chemistry Reference: HEXA-4,5-DIEN-1-OL(40365-64-8)
• EPA Substance Registry System: HEXA-4,5-DIEN-1-OL(40365-64-8)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 40365-64-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H10O/c1-2-3-4-5-6-7/h3,7H,1,4-6H2

Upstream product

• 72038-66-5 4,5-hexadien-1-yl trimethylsilyl ether 
• 928-90-5 5-hexyl-1-ol 
• 764-60-3 hex-2-yn-1-ol 
• 50-00-0 formaldehyd 
• 5390-04-5 pent-1-yn-5-ol 
• 108207-73-4 1-Trimethylsilanyl-6-trimethylsilanyloxy-hex-2-yne 
• 82430-89-5 1,1-dibromo-2-<3-(trimethylsiloxy)propyl>cyclopropane 
• 76711-41-6 1-(Trimethylsilyl)-2-hexyn-6-ol 
• 373-61-5 boron trifluoride diacetate 
• 72051-04-8 6-(toluene-4-sulfonyloxy)-hexa-1,2-diene 
• 821-09-0 n-Pent-4-enyl alcohol 
• 75-25-2 Bromoform 
• 60857-52-5 2-hexa-4,5-dienyloxy-tetrahydro-pyran 

Downstream Products

• 72038-67-6 hexa-4,5-dienoic acid 
• 107970-37-6 N-(hexa-4,5-dien-1-yl)-4-methylbenzenesulfonamide 

Relevant articles and documents

Palladium catalysed tetramolecular queuing cascades of aryl iodides, carbon monoxide, amines and a polymer supported allene

Chemo- and regio-specific palladium catalysed four component processes, involving formation of 3 new bonds, initiated by oxidative addition of Pd(0) with aryl iodides followed by sequential incorporation of CO (1 atm), a polymer supported allene and an am

Medium and Large N-Heterocycle Formation via Allene Hydroamination with a Bimetallic Rh(II) Catalyst

We report the synthesis of a 2-phosphinoimidazole-derived bimetallic Rh(II) complex that enables intramolecular allene hydroamination to form 7- to 10-member rings in high yield. Monometallic Rh complexes, in contrast, fail to achieve any product formatio

Enantioselective Rhodium-Catalyzed Dimerization of ω-Allenyl Carboxylic Acids: Straightforward Synthesis of C2-Symmetric Macrodiolides

Herein, we report on the first enantioselective and atom-efficient catalytic one-step dimerization method to selectively transform ω-allenyl carboxylic acids into C2-symmetric 14- to 28-membered bismacrolactones (macrodiolides). This convenient asymmetric access serves as an attractive route towards multiple naturally occuring homodimeric macrocyclic scaffolds and demonstrates excellent efficiency to construct the complex, symmetric core structures. By utilizing a rhodium catalyst with a modified chiral cyclopentylidene-diop ligand, the desired diolides were obtained in good to high yields, high diastereoselectivity, and excellent enantioselectivity.

Stereoselective synthesis of chiral polycyclic indolic architectures through Pd0-catalyzed tandem deprotection/cyclization of tetrahydro-β-carbolines on allenes

Enantioenriched N-allyl tetrahydro-β-carbolines were prepared by chiral phosphoric acid-catalyzed Pictet-Spengler reactions. The compounds undergo Pd0-catalyzed cyclizations through a tandem deprotection/cyclization process. The regioselectivit