403665-98-5Relevant academic research and scientific papers
GaCl3-promoted ethenylation of thioester silyl enolate and dienolate with silylethyne
Arisawa, Mieko,Miyagawa, Chie,Yoshimura, Satoru,Kido, Yoshiyuki,Yamaguchi, Masahiko
, p. 1080 - 1081 (2007/10/03)
In the presence of GaCl3, silyl enol ethers derived from either S-alkyl or S-aryl thioesters are ethenylated at the α-carbon atom with trimethylsilylethyne in high yields. The reactions of dienolates give α,α-diethenyl thioesters.
