403738-05-6Relevant articles and documents
Stereospecific entry to [4.5]spiroketal glycosides using alkylidenecarbene C-H insertion.
Wardrop, Duncan J,Zhang, Wenming,Fritz, Joseph
, p. 489 - 492 (2002)
[reaction: see text] A novel method for the stereospecific preparation of [4.5]spiroketal glycosides utilizing the 1,5 C-H bond insertion of alkylidenecarbenes is described. Treatment of 2-oxopropyl beta-pyranosides A with lithium (trimethylsilyl)diazomet