403986-41-4

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 300830-78-8 (1S,6S)-6-{[(1,1-dimethylethyl)diphenylsilyl]oxy}-2-iodocyclohexa-2,4-dien-1-ol 

Downstream Products

• 127545-53-3 (4R,5R,6S)-4,5,6-trihydroxy-2-methyl-2-cyclohexen-1-one 
• 403986-44-7 (3aR,4R,7aR)-4{[(1,1-dimethylethyl)diphenylsilyl]oxy}-3a,7a-dihydro-6-iodo-2,2-dimethyl-1,3-benzodioxol-5(4H)-one 
• 403986-45-8 (3aR,4R,7aR)-4{[(1,1-dimethylethyl)diphenylsilyl]oxy}-3a,7a-dihydro-2,2,6-trimethyl-1,3-benzodioxol-5(4H)-one 
• 231934-87-5 (3aR,4R,5S,7aR)-4{[(1,1-dimethylethyl)diphenylsilyl]oxy}-3a,4,5,7a-tetrahydro-6-iodo-2,2-dimethyl-1,3-benzodioxol-5-ol 

Relevant academic research and scientific papers

A concise and chemoenzymatic synthesis of (-)-gabosine A, a carba-sugar enone from Streptomycetes

The title compound 1 has been prepared, for the first time, in six steps and a completely stereo-controlled fashion from the cis-1,2-dihydrocatechol 3. The starting material is a readily available and enantiopure compound that can be obtained in large qua

Syntheses of the D-aldopentoses from non-carbohydrate sources

The cis-1,2-dihydrocatechols 5-7, which are obtained in high yield and ca. 99.8% ee by microbial oxidation of the corresponding aromatic compound, have been converted, via reaction sequences involving three distinct types of one-carbon deletion processes, into the four D-aldopentoses.