40411-90-3Relevant academic research and scientific papers
A diruthenium μ-carbido complex that shows singlet-carbene-like reactivity
Takemoto, Shin,Ohata, Jun,Umetani, Kento,Yamaguchi, Masahiro,Matsuzaka, Hiroyuki
, p. 15889 - 15892 (2014)
Low-temperature deprotonation of the cationic μ-methylidyne complex [(CpRu)2(μ-NPh)(μ-CH)][BF4] (Cp = η5-C5Me5) with KN(SiMe3)2 affords a thermally unstable μ-carbido complex [(C
Parent Cyclopentadienyl Ruthenium(II) Chloride Synthon: Derivatization to CpRu Amido, Imido, and Oxo Complexes
Takemoto, Shin,Ishii, Hana,Yamaguchi, Masahiro,Teramoto, Akira,Tsujita, Masayuki,Ozeki, Daiki,Matsuzaka, Hiroyuki
, p. 4298 - 4306 (2019)
The complex salt [CpRu(??6-C10H8)][(CpRu)2(μ-Cl)3] ([1][2]) was synthesized and found to be a useful CpRuCl synthon. The ions [1]+ and [2]- cleanly comproportionate into monomeri
Synthesis of a mixed phosphonium-sulfonium bisylide R3P=C= SR2
Pascual, Sergio,Asay, Matthew,Illa, Ona,Kato, Tsuyoshi,Bertrand, Guy,Saffon-Merceron, Nathalie,Branchadell, Vicenc,Baceiredo, Antoine
, p. 9078 - 9080 (2008/09/20)
Mixing it up: The first persistent mixed phosphorus-sulfur bisylide has been synthesized (see scheme). Its formation was clearly demonstrated by its chemical reactivity, such as by methylation and complexation with CuI ions. DFT calculations on a model compound indicate that they are highly polarized species as a result of the interaction of the lone pairs of electrons on the central carbon atom with only the phosphonium function. (Chemical Equation Presented).
