404369-59-1Relevant academic research and scientific papers
Copper-catalyzed regioselective 2-amination of o-haloanilides with aqueous ammonia
Tang, Yan-Ling,Li, Mei-Ling,Gao, Jin-Chun,Sun, Yun,Qu, Lu,Huang, Feng,Mao, Ze-Wei
supporting information, (2021/04/02)
An efficient Cu(II)-vasicine catalytic system has been developed for intramolecular C[sbnd]N bond formation. In this way, regioselective 2-amination of o-haloanilides with aqueous ammonia in EtOH has been achieved. This strategy provides several advantages, such as good regioselectivity, high yields and functional group tolerance.
Microwave-assisted acylation of amines, alcohols, and phenols by the use of Solid-Supported Reagents (SSRs)
Petricci, Elena,Mugnaini, Claudia,Radi, Marco,Corelli, Federico,Botta, Maurizio
, p. 7880 - 7887 (2007/10/03)
A microwave-assisted synthesis of solid-supported reagents for the acylation of amines has been developed, and the same methodology has been successfully applied to the preparation of acylating agents anchored on different solid supports. Similarly, alcohols, phenols, and thiophenols have been easily acylated using these reagents under microwave irradiation.
