40468-55-1Relevant academic research and scientific papers
Th(IV) complexes with cis-ethylenebis(diphenylphosphine oxide): X-ray structures and NMR solution studies
Morse, Paul T.,Staples, Richard J.,Biros, Shannon M.
, p. 2 - 12 (2016)
The complexation of Th(NO3)4 with the rigid diphosphoryl ligand cis-ethylenebis(diphenylphosphine oxide) has been investigated using X-ray crystallography, IR, NMR and CHN analysis. Three crystal polymorphs were grown out of methanol
Preparation of organohalosilanes
-
, (2008/06/13)
In an industrial process for preparing organohalosilanes by reacting metallic silicon particles with an organohalide in the presence of a copper catalyst, a contact mass composed of the metallic silicon and the catalyst further contains an effective amount of a phosphine chalcogenide compound. The invention drastically increases the silane formation rate and the utilization of silicon without lowering the selectivity of useful silane.
Investigation into Diphosphine Oxides as Ligands in Diorganotin(IV) Adducts. Part 3. Synthesis and Crystal Structure of Two Adducts of Dinitratodiphenyltin(IV) with cis- and trans-1,2-Bis(diphenylphosphoryl)ethylene
Dondi, Stefano,Nardelli, Mario,Pelizzi, Corrado,Pelizzi, Giancarlo,Predieri, Giovanni
, p. 487 - 492 (2007/10/02)
The co-ordinating properties of cis- and trans-1,2-bis(diphenylphosphoryl)ethylene (cdppoet and tdppoet respectively) have been examined in two new organotin(IV) complexes, SnPh2(NO3)2(cdppoet)*CHCl3 (1) and 2(tdppoet)*H2O (2), on both of whi
