4048-78-6Relevant academic research and scientific papers
Palladium Complexes Bearing Mesoionic Carbene Ligands: Applications in α-Arylation, α-Methylation and Suzuki-Miyaura Coupling Reactions
Maity, Ramananda,Verma, Amit,Van Der Meer, Margarethe,Hohloch, Stephan,Sarkar, Biprajit
, p. 111 - 117 (2016)
Complexes of mesoionic carbene (MIC) ligands are gaining immense popularity in organometallic chemistry and homogeneous catalysis. We present here a series of palladium(II) complexes that are comprised of MIC donor ligands, and we demonstrate their applic
Synthesis of Novel Heterocycles by Amide Activation and Umpolung Cyclization
Maulide, Nuno,Riomet, Margaux,Roller, Alexander,Zhang, Haoqi
, (2020/03/24)
Herein, we report a metal-free synthesis of cyclic amidines, oxazines, and an oxazinone under mild conditions by electrophilic amide activation. This strategy features an unusual Umpolung cyclization mode and enables the smooth union of α-aryl amides and diverse alkylazides, effectively rerouting our previously reported α-amination transform.
Imidazo[2,2-b][3]benzazepine and pyrimido[2,1-b][3]benzazepine antiarrhythmic agents
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, (2008/06/13)
Novel imidazo[2,1-b][3]benzazepines and pyrimido[2,1-b][3]benzazepines of formula I, pharmaceutical compositions containing them, methods for treating cardiac arrhythmia in mammals utilizing them, and processes for synthesizing them. STR1
