404891-66-3Relevant academic research and scientific papers
Asymmetric synthesis of deoxypolypropionate units via stereoselective hydrogenation of optically active cycloheptatriene
Sugimura, Takashi,Sato, Yasuhiro,Im, Chun Young,Okuyama, Tadashi
, p. 4439 - 4442 (2004)
(Chemical equation presented) Optically active polypropionate units were synthesized in 9-11 steps from 3,5-dimethylphenol. The sequence consists of the Buechner reaction controlled by a chiral 2,4-pentanediol tether and diastereoselective hydrogenation o
Stereoselective hydrogenation of conjugate diene directed by?hydroxy group and asymmetric synthesis of deoxypolypropionate units
Sugimura, Takashi,Im, Chun Young,Sato, Yasuhiro,Okuyama, Tadashi
, p. 4027 - 4038 (2007/10/03)
Optically active cyclic compounds carrying a conjugate diene and two hydroxy groups were prepared through the intramolecular Büchner reaction with a chiral tether and succeeding stereoselective conversion. Hydrogenation of the diene in the first step was
