404937-08-2Relevant academic research and scientific papers
The synthesis and metal coordination chemistry of a novel phosphine- and thiolate-substituted ferrocenediyl ligand
Gibson, Vernon C.,Long, Nicholas J.,White, Andrew J.P.,Williams, Charlotte K.,Williams, David J.
, p. 770 - 772 (2002)
The synthesis and metal coordination chemistry of a phosphine- and thiolate-substituted ferrocenediyl ligand were discussed. Bridged dimeric species, with the thiolate S adopting a binucleating role were found to be observed for Pd(II) and Rh(I) metal centers while a mononuclear, square planar Ni(II) complex was formed on reaction of the ligand with [Ni-(TMEDA)Me2]. It was found that the rhodium complexes with phosphorus-sulfur donor ligands showed excellent activities and stability as methanol carbonylation catalysts.
