405060-39-1

Basic information

• Product Name: 2,3,4,6-tetra-O-benzyl-1-deoxy-1-thio-α-D-galactopyranose
• Synonyms: 2,3,4,6-tetra-O-benzyl-1-deoxy-1-thio-α-D-galactopyranose
• CAS NO: 405060-39-1
• Molecular Weight: 556.723
• Mol File: 405060-39-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2,3,4,6-tetra-O-benzyl-1-deoxy-1-thio-α-D-galactopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,6-tetra-O-benzyl-1-deoxy-1-thio-α-D-galactopyranose(405060-39-1)
• EPA Substance Registry System: 2,3,4,6-tetra-O-benzyl-1-deoxy-1-thio-α-D-galactopyranose(405060-39-1)

Safety Data

• Hazardous Substances Data: 405060-39-1(Hazardous Substances Data)

Upstream product

• 893421-26-6 bis[2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl]disulfide 
• 6386-24-9 2,3,4,6-tetra-O-benzyl-D-galactopyranose 
• 405060-38-0 1-S-thio-(p-nitrobenzoyl)-2,3,4,6-tetra-O-benzyl-α-D-galactopyranoside 
• 405060-35-7 2,3,4,6-tetra-O-benzyl-1-O-[((p-nitrobenzoyl)sulfanyl)thiocarbonyl]-α-D-galactopyranose 
• 74-88-4 methyl iodide 

Downstream Products

• 893421-28-8 [10-((2R,3R,4S,5S,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylsulfanyl)-decyl]-phosphonic acid diethyl ester 
• 899430-10-5 12-((2R,3R,4S,5S,6R)-3,4,5-Tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-ylsulfanyl)-dodecan-1-ol 
• 893421-29-9 10-hydroxydecyl 2,3,4,6-tetra-O-benzyl-1-thio-α-D-galactopyranoside 

Relevant articles and documents

Unusual anomeric rearrangement of para-nitrobenzoylxanthate d-glycosides: a new direct stereoselective access to α-thioglycosides from pyranose sugars

A mild and general procedure for the synthesis of α-thioglycosides from glycopyranoses is described. The method involves the treatment of pyranose reductive sugar with sodium hydride, carbon disulfide, and p-nitrobenzoyl chloride, as a key step, to yield

Rearrangement of 1-O-(thio-p-nitrobenzoyl)thiocarbonyl galactoside: A novel access to α-thioglycoside derivatives

The synthesis of galactosides thiolate and thioester is described by direct S-glycosylation process from 1-O-(thio-p-nitrobenzoyl)thiocarbonyl galactoside. Three novel anomeric groups are presented as potent glycoside activators: O-(thio-p-nitrobenzoyl)th