405139-86-8

Basic information

• Product Name: O-(β-D-glucopyranosyl)-2-diphenylphosphanylbenzaldoxime
• Synonyms: O-(β-D-glucopyranosyl)-2-diphenylphosphanylbenzaldoxime
• CAS NO: 405139-86-8
• Molecular Weight: 467.458
• Mol File: 405139-86-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: O-(β-D-glucopyranosyl)-2-diphenylphosphanylbenzaldoxime(CAS DataBase Reference)
• NIST Chemistry Reference: O-(β-D-glucopyranosyl)-2-diphenylphosphanylbenzaldoxime(405139-86-8)
• EPA Substance Registry System: O-(β-D-glucopyranosyl)-2-diphenylphosphanylbenzaldoxime(405139-86-8)

Safety Data

• Hazardous Substances Data: 405139-86-8(Hazardous Substances Data)

Upstream product

• 143658-69-9 1-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)pyrrolidine-2,5-dione 
• 50777-76-9 (2-formylphenyl)(diphenyl)phosphine 
• 390756-31-7 O-(β-D-glucopyranosyl)hydroxylamine 

Relevant articles and documents

Enantioselective catalysis. Part 142: Carbohydrate-derived oxime ethers from functionalised aldehydes and O-β-D-glucopyranosylhydroxylamine - New C=N ligands stable towards hydrolysis

A new way of linking carbohydrates to phosphorus- or nitrogen-containing aldehydes via oxime ethers is described resulting in novel C=N ligands which are stable towards hydrolysis. Reaction of O-β-D-glucopyranosylhydroxylamine 2 with 2-diphenylphosphanylbenzaldehyde 3 or pyridine-2-carbaldehyde 4 afforded the oxime ethers O-(β-D-glucopyranosyl)-2-diphenylphosphanylbenzaldoxime 5 and O-(β-D-glucopyranosyl)pyridine-2-carbaldoxime 6. After peracetylation of the hydroxyl groups in 5 and 6, the protected sugar derivatives O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-2- diphenylphosphanylbenzaldoxime 7 and O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)pyridine-2-carbaldoxime 8 were obtained. The molecular structure of 7 was established by X-ray diffraction studies.