405156-28-7Relevant academic research and scientific papers
Application of intramolecular carbonyl-ene reaction towards the synthesis of idarubicinone scaffold
Basak, Shyam,Ray, Sutapa,Mal, Dipakranjan
, p. 257 - 269 (2018/07/05)
Intramolecular aromatic carbonyl-ene reaction (ICE)has been combined with a modified Hauser annulation to offer a facile access to the tetracyclic idarubicinone core. The required key dihydroxyanthraquinone aldehyde precursor was assembled in one step by
The synthesis of isochroman-4-ols and isochroman-3-ols: Models for naturally occurring benzo[g]isochromanols
De Koning, Charles B,Green, Ivan R,Michael, Joseph P,Oliveira, José R
, p. 9623 - 9634 (2007/10/03)
The synthesis of isochromanes containing hydroxy substituents at the 4- and 3-positions has been achieved. The key step for the synthesis of the isochroman-4-ols entailed an oxidative mercury mediated ring closure of 2-(prop-1-enyl)phenylmethanol derivati
