405171-25-7Relevant academic research and scientific papers
Rearrangements of cyclobutenones. Electrocyclic ring closure and thermal ring expansions of 3-allenyl- and 3-alkynyl-2-dienyl-4,4-dimethoxycyclobutenones
Hergueta, Antonio R.,Moore, Harold W.
, p. 1388 - 1391 (2007/10/03)
Thermal rearrangements of 2-allenyl- and 2-alkynyl-3-(2-ethenylphenyl)-4,4-dimethoxycyclobutenones were studied. At ambient temperature, the allenyl compounds undergo an electrocyclic cascade to give bicyclo[4.2.0]-octadienyl-fused cyclobutenones. These u
