405236-05-7Relevant academic research and scientific papers
Synthesis of a trigalacturonic acid analogue mimicking the expected transition state in the glycosidases
Yamamoto, Kazunori,Noguchi, Shogo,Takada, Noboru,Miyairi, Kazuo,Hashimoto, Masaru
experimental part, p. 572 - 585 (2010/10/04)
A trigalacturonic acid analogue carrying a cyclohexene framework in place of the central pyranose ring was synthesized as a molecular probe for the mechanistic investigation of endo-polygalacturonase 1 (endo-PG 1). Preliminary enzymatic studies revealed t
Solid-phase capture-release strategy applied to oligosaccharide synthesis on a soluble polymer support
Ando, Hiromune,Manabe, Shino,Nakahara, Yoshiaki,Ito, Yukishige
, p. 4725 - 4728 (2007/10/03)
A highly simplified synthesis of a tetrasaccharide was possible by a repeated coupling/capture-release cycle. In the first cycle, a glycosyl acceptor (1) bound to a soluble polymer reacted with a glycosyl donor (2) having a chloroacetyl group as a tempora
