405282-85-1

Upstream product

• 821-09-0 n-Pent-4-enyl alcohol 
• 1219934-69-6 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl ortho-(hex-1-ynyl)benzoate 

Downstream Products

• 405283-35-4 (3aR,5R,6R,7S,7aR)-6,7-Bis-benzyloxy-5-benzyloxymethyl-2-methyl-2-pent-4-enyloxy-tetrahydro-[1,3]dioxolo[4,5-b]pyran 
• 286425-50-1 (2R,3R,4S,5R,6R)-3,4-Bis-benzyloxy-2-benzyloxymethyl-6-pent-4-enyloxy-5-(3,4,5-trimethoxy-benzyloxy)-tetrahydro-pyran 
• 286425-51-2 (2R,3R,4R,4aS,10bR)-3,4-Bis-benzyloxy-2-benzyloxymethyl-8,9,10-trimethoxy-2,3,4,4a,6,10b-hexahydro-pyrano[3,2-c]isochromene 
• 286425-53-4 (2R,3R,4R,4aS,10bS)-3,4-Bis-benzyloxy-2-benzyloxymethyl-8,9,10-trimethoxy-2,3,4,4a,6,10b-hexahydro-pyrano[3,2-c]isochromene 
• 130781-26-9 4-Pentenyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside 

Relevant academic research and scientific papers

Identification of 3,6-di-O-acetyl-1,2,4-O-orthoacetyl-α-d- glucopyranose as a direct evidence for the 4-O-acyl group participation in glycosylation

The formation of 3,6-di-O-acetyl-1,2,4-O-orthoacetyl-α-d- glucopyranose was observed in the gold(i)-catalyzed glycosidation of peracetyl glucopyranosyl ortho-hexynylbenzoate; experiments with substrates bearing deuterium labeled 2-O-acetyl or 4-O-acetyl groups indicated that the orthoacetate was derived from the 4-O-acetyl group, which provided a direct evidence for the remote participation of the 4-O-acyl group in glycosylation.