40543-62-2Relevant academic research and scientific papers
Biocatalytic Site-Selective Hydrogen Isotope Exchange of Unsaturated Fragments with D2O
Wang, Lanlan,Lou, Yujiao,Xu, Weihua,Chen, Zhichun,Xu, Jian,Wu, Qi
, p. 783 - 788 (2022/01/15)
Deuterated unsaturated fragments have gained increasing attention because of their roles in understanding reaction mechanisms and pharmaceutical potentials. Due to the difficulties of the existing synthetic methods, it is highly desirable to develop an ef
Unifying the mechanisms for alkane dehydrogenation and alkene H/D exchange with [IrH2(O2CCF3)(PAr3)2]: The key role of CF3CO2 in the "sticky" alkane route
Gerard,Eisenstein,Lee,Chen,Crabtree
, p. 1121 - 1131 (2007/10/03)
To understand photochemical and thermal alkane activation with IrH2(O2CCF3)(PAr3)2 (Ar = p-FC6H4), H/D isotope scrambling between alkenes and IrD2(O2CCFsub
The Mechanism of the Clemmensen Reduction: the Substartes
Burdon, James,Price, Robin C.
, p. 893 - 894 (2007/10/02)
Product analysis and deuterium labelling experiments suggest that the critical intermediate in the reduction of ArCOCH2R with Zn/HCl is a zinc-carbene; this may be protonated to give ArCH2CH2R, converted into ArCH=CHR by rearrangement, deprotonated to give a vinyl-zinc species, or captured by an alkene to give a cyclopropane.
