405519-75-7Relevant academic research and scientific papers
SYNTHESIS OF DIAZONAMIDE "A" CORE
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Page 8; 13, (2010/11/30)
Using a novel samarium (II)-based macrocyclization cascade reaction, the entire highly strained ABCDEF aromatic core of diazonamide "A" and several novel analogies thereof are constructed.
Construction of the complete aromatic core of diazonamide A by a novel hetero pinacol macrocyclization cascade reaction
Nicolaou,Huang, Xianhai,Giuseppone, Nicolas,Rao, Paraselli Bheema,Bella, Marco,Reddy, Mali V.,Snyder, Scott A.
, p. 4705 - 4709 (2007/10/03)
One of the most enticing natural products isolated in recent years and a serious challenge to synthetic chemists is represented by the potent anticancer agent diazonamide A (1). By utilizing a highly convergent approach, the ABCDEF macrocycle 2 was constr
