40576-40-7Relevant academic research and scientific papers
Synthesis of (3S*,4R*,6E,10Z)-3,4,7,11-tetramethyltrideca6,10-dienal (faranal) using stereospecific 1,4-cis-hydrogenation of conjugated double bonds
Vasil'ev, Andrei A.,Engman, Lars,Serebryakov, Edward P.
, p. 2211 - 2216 (2000)
(±)-Faranal was synthesised by a convergent route involving 1,4-cis-hydrogenation of two properly substituted conjugated diene building blocks to introduce stereospecifically the 6(E) and 10(Z) double bonds of the final target molecule. meso-2,3-Dimethyls
Regio- and Stereoselective Allylic Substitutions of Chiral Secondary Alkylcopper Reagents: Total Synthesis of (+)-Lasiol, (+)-13-Norfaranal, and (+)-Faranal
Skotnitzki, Juri,Spessert, Lukas,Knochel, Paul
, p. 1509 - 1514 (2019/01/05)
Chiral secondary alkylcopper reagents were prepared from chiral secondary alkyl iodides by a retentive I/Li exchange followed by a retentive transmetalation with CuBr?P(OEt)3. Switching the solvent to THF significantly increased their configura
