405877-18-1Relevant academic research and scientific papers
An improved catalyst for the asymmetric arylation of ketone enolates
Hamada, Takayuki,Chieffi, Andre,Ahman, Jens,Buchwald, Stephen L.
, p. 1261 - 1268 (2002)
A new catalyst system for the enantioselective α-arylation of ketones is reported. This catalyst, prepared from Pd2(dba)3 and a bulky dialkylphosphino-binaphthyl ligand, is able to effect the asymmetric arylation of ketone enolates w
Catalytic asymmetric vinylation of ketone enolates.
Chieffi,Kamikawa,Ahman,Fox,Buchwald
, p. 1897 - 1900 (2007/10/03)
[see reaction]. A protocol for the catalytic asymmetric vinylation of ketone enolates has been developed. Key to the success of this process was the development of new electron-rich chiral monodentate ligands.
