405887-49-2Relevant academic research and scientific papers
Mono- and zerovalent manganese alkyl complexes supported by the α,α′-diiminato pyridine ligand: Alkyl stabilization at the expense of catalytic performance
Reardon, Damien,Aharonian, Ghazar,Gambarotta, Sandro,Yap, Glenn P.A.
, p. 786 - 788 (2002)
The mono- and zerovalent manganese alkyl complexes supported by the α,α′-diiminato pyridine ligand were analyzed. The reactivity pattern provides both activation of the vanadium metal and a two electron reduction pathway towards rare monovalent vanadium alkyls. The coordination geometry of manganese was identical to that of the Fe and Co supercatalysts with the same distorted square pyramidal arrangement.
