40603-50-7Relevant academic research and scientific papers
Intermetallic chalcogenide atom transfer and the synthesis of 1,4-[(CH3C5H4)2Ti]2S 4
Mark Bolinger,Hoots, John E.,Rauchfuss, Thomas B.
, p. 223 - 225 (2008/10/08)
(C6H4R)2TiE5 (R = H, CH3; E = S, Se) efficiently transfer a dichalcogenide fragment to [Ir(Ph2PCH2CH2PPh2)2]Cl affording IrIIIE2 complexes and in one case 1,4-[(C5H4CH3)2Ti]2S 4. The unique Ti2S4 heterocycle can also be prepared via the PBu3 desulfurization of (C5H4CH3)2TiS5.
