40644-11-9Relevant articles and documents
The Mechanism of the Reactions of Alkoxy- and Aryloxytrimethylsilanes with Sulfinyl Chlorides. A Doubt about 4-Center Mechanism for the Bimolecula IVb-VIb Bond Cleavages
Kozuka, Seizi,Higashino, Tetsuji
, p. 1183 - 1185 (2007/10/02)
Kinetic studies have been conducted for the reactions of ethoxytrimethylsilane with benzenesulfinyl chloride and aryloxytrimethylsilane with methanesulfinyl chloride.Both the reactions were found to obey second order rate equation.A clear negative ρ value was observed for the reaction of aryloxytrimethylsilane.The solvent effects suggested that both the two reactions were quite similar in their mechanisms.Nucleophilic addition of silyl-oxygen atom to sulfinyl group has been suggested for these two reactions.