40648-22-4

Basic information

• Product Name: Cyclohexene, 3-bromo-1-methyl-
• CAS NO: 40648-22-4
• Molecular Formula: C7H11Br
• Molecular Weight: 175.068
• Mol File: 40648-22-4.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 3-bromo-1-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 3-bromo-1-methyl-(40648-22-4)
• EPA Substance Registry System: Cyclohexene, 3-bromo-1-methyl-(40648-22-4)

Safety Data

• Hazardous Substances Data: 40648-22-4(Hazardous Substances Data)

Upstream product

• 930-68-7 cyclohexenone 
• 23758-27-2 1-methylcyclohex-2-en-1-ol 
• 591-49-1 1-methylcyclohex-1-ene 
• 21378-21-2 3-methylcyclohex-2-en-1-ol 

Downstream Products

• 20053-43-4 α-(3-Methyl-cyclohex-2-en-1-yl)-malonsaeurediethylester 
• 864870-18-8 (1-methylcyclohex-2-enyl)phenylmethanol 
• 1489-57-2 2-methylcyclohexa-1,3-diene 
• 1489-56-1 1-methyl-1,3-cyclohexadiene 
• 1219117-78-8 C₁₃H₁₅F 
• 1219117-85-7 C₁₀H₁₈ 
• 13828-31-4 m-menth-1-ene 
• 869287-15-0 α,α,3-trimethyl-2-cyclohex-2-enylacetic acid 
• 869287-12-7 2-(3-methylcyclohex-2-enyl)-2,2-dimethylethanol 
• 181061-05-2 methyl 2,2-dimethyl-2-(3'-methyl-2'-cyclohexen-1'-yl)acetate 

Relevant articles and documents

Guanidine–Copper Complex Catalyzed Allylic Borylation for the Enantioconvergent Synthesis of Tertiary Cyclic Allylboronates

An enantioconvergent synthesis of chiral cyclic allylboronates from racemic allylic bromides was achieved by using a guanidine–copper catalyst. The allylboronates were obtained with high γ/α regioselectivities (up to 99:1) and enantioselectivities (up to 99 % ee), and could be further transformed into diverse functionalized allylic compounds without erosion of optical purity. Experimental and DFT mechanistic studies support an SN2′ borylation process catalyzed by a monodentate guanidine–copper(I) complex that proceeds through a special direct enantioconvergent transformation mechanism.

Mild two-step process for the transition-metal-free synthesis of carbon-carbon bonds from allylic alcohols/ethers and grignard reagents

Chemical Equation Represented A mild two-step process for the regioselective, transition-metal-free preparation of carbon-carbon bonds from allylic alcohols/ethers and Grignard reagents is described. This process obviates the need for the harsh deprotecti

Initiated tert-Butyl Hydroperoxide-loaded Low-temperature Autoxidation of Alkenes: Alternative Hydroperoxide Syntheses and the Preparation of a Complete Set of Reference Material

A complete set of characterization data for the allylic hydroperoxides prepared from 1-methylcyclohexene and the isomeric 4-methyloct-4-enes is presented.The data relies upon the preparation of allylic hydroperoxides by tert-butyl hydroperoxide-loaded autoxidations, singlet-ene oxidations and nucleophilic substitution reactions.Appropriate allylic alcohols and relevant scission products have been prepared to support the assignments given.