406485-68-5Relevant academic research and scientific papers
Chiral Ferrocenyl N,N Ligands with Intramolecular Hydrogen Bonds for Highly Enantioselective Allylic Alkylations
Yao, Lin,Nie, Huifang,Zhang, Dongxu,Wang, Libin,Zhang, Yuhao,Chen, Weiping,Li, Zhenhua,Liu, Xueying,Zhang, Shengyong
, p. 804 - 809 (2018)
Several new ferrocene-derived bidentate N ligands, which contain multiple chiral factors, have been designed and synthesized by a rational combination of oxazoline and pyridine. Their catalytic performances were investigated preliminarily in Pd-catalyzed
Chiral N-(tert-butyl)-N-methylaniline type ligands: synthesis and application to palladium-catalyzed asymmetric allylic alkylation
Mino, Takashi,Asakawa, Minato,Shima, Yamato,Yamada, Haruka,Yagishita, Fumitoshi,Sakamoto, Masami
, p. 5985 - 5993 (2015)
Abstract We found that N-(tert-butyl)-N-methylanilines 1 have C(aryl)-N(amine) bond axial chirality and succeeded the optical resolution of C-N bond atropisomers of amines 1 by a chiral palladium resolving agent and/or a chiral HPLC method. Finally, we de
CYCLIC IMIDATE LIGANDS
-
Page/Page column 21, (2012/04/05)
The present invention relates to a use of a cyclic imidate as a ligand for catalysis in which the ligand contains sub-structure (Y) as a minimal structural motive, wherein the carbon atoms and the nitrogen atom can be optionally substituted by a chemical substituent.
