406502-48-5

Basic information

• Product Name: (η5-1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium hexafluorophosphate
• CAS NO: 406502-48-5
• Molecular Weight: 779.631
• Mol File: 406502-48-5.mol

Chemical Properties

• CAS DataBase Reference: (η5-1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium hexafluorophosphate(CAS DataBase Reference)
• NIST Chemistry Reference: (η5-1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium hexafluorophosphate(406502-48-5)
• EPA Substance Registry System: (η5-1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl)bis(acetonitrile)(triphenylphosphine)ruthenium hexafluorophosphate(406502-48-5)

Safety Data

• Hazardous Substances Data: 406502-48-5(Hazardous Substances Data)

Upstream product

• 406502-40-7 (η5-1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl)tris(acetonitrile)ruthenium hexafluorophosphate 
• 603-35-0 triphenylphosphine 

Relevant articles and documents

A facile route to 1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl ruthenium half- and mixed-sandwich compounds

A series of half- and mixed-sandwich (Cp? = 1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienide) ruthenium compounds have been synthesized from a new Cp?Ru synthon, [Cp?Ru(NCCH3)3](PF6). [Cp?Ru-(NCCH3)3J(PF6) is efficiently generated by photolysis of [Cp?RuBz](PF6) in acetonitrile with a quantum yield of approximately 0.34. The methods described here should be useful for the synthesis of other compounds that contain the Cp?Ru group.