406674-56-4Relevant academic research and scientific papers
Synthesis of highly reactive organosulfur compounds
Okazaki, Renji,Goto, Kei
, p. 414 - 418 (2002)
Application of novel bowl-type and dendrimer-type steric protection groups to the first synthesis of stable aromatic S-nitrosothiols is described. These compounds showed remarkable thermal stability whereas they easily reacted with appropriate reagents. X-ray crystallographic analysis established their structures, where the C-S-N-O linkage adopts only the syn conformation. Synthesis of a stable sulfenic acid by taking advantage of the bowl-type substituent is also delineated.
Synthesis, Structure, and Reactions of the First Stable Aromatic S-Nitrosothiol Bearing a Novel Dendrimer-Type Steric Protection Group
Goto, Kei,Hino, Yoko,Takahashi, Yusuke,Kawashima, Takayuki,Yamamoto, Gaku,Takagi, Nozomi,Nagase, Shigeru
, p. 1204 - 1205 (2007/10/03)
A stable aromatic S-nitrosothiol was synthesized by taking advantage of a novel dendrimer-type steric protection group, and its structure was determined by X-ray crystallographic analysis. Its reactions including oxidation to a stable S-nitrothiol are described.
