406911-89-5Relevant articles and documents
Synthesis and catalytic activity of a Grubbs-Hoveyda pre-catalyst having a trimeric resting state
Liu, Guiyan,Wu, Bin,Wang, Jianhui
, p. 441 - 445 (2015/04/22)
A Grubbs-Hoveyda pre-catalyst having a trimeric resting state based on 2,4,6-trichloro-1,3,5-triazine was synthesized and the complex was characterized by NMR, HRMS and elemental analysis. The activity of this complex for ring-closing metathesis (RCM) was
Efficient ruthenium metathesis catalysts containing carborane ligands
Liu, Guiyan,Zhang, Huizhu,Zhao, Xia,Wang, Jianhui
, p. 13 - 17 (2013/10/22)
A first generation Hoveyda-Grubbs ruthenium complex with a closo-1,2-C 2B10H11 tag has been prepared. This new catalyst was tested in ring-closing metathesis (RCM) reactions and proved to be quite efficient. In addition, t
Recycling a homogeneous catalyst through a light-controlled phase tag
Liu, Guiyan,Wang, Jianhui
supporting information; experimental part, p. 4425 - 4429 (2010/08/07)
(Figure Presented) A homogeneous ruthenium-carbene complex was tagged with a lightresponding nitrobenzospiropyran group to control its solubility through reversible conversion between its neutral (lipophilic) and ionic (lipophobic) states using light irradiation (see scheme; Mes = mesityl). This tagged complex has significant catalytic activity in ring-closing metathesis reactions and was recycled several times.