40727-31-9Relevant academic research and scientific papers
HYDROGENATION OF 7-METHYLENEBICYCLONONAN-3-ONE OVER GROUP VIII METAL CATALYSTS. NOVEL REDUCTIVE CYCLIZATION
Ishiyama, Jun-ichi,Senda, Yasuhisa,Imaizumi, Shin
, p. 771 - 774 (2007/10/02)
The products of novel reductive cyclization, 1-adamantanol and 1-methyl-2-oxa-adamantane, were obtained in the hydrogenation of 7-methylenebicyclononan-3-one over group VIII metal black catalysts in ethanol or cyclohexane. 1-Adamantanol was produced over Pd, Rh, Co and Ni catalysts, and 1-methyl-2-oxa-adamantane only over Co catalysts in cyclohexane.
CATALYTIC HYDROGENATION OF 7-METHYLBICYCLONON-6-EN-3-ONE. ANOMALOUSLY HIGH SELECTIVITIES ON Pd AND Co BLACK CATALYSTS
Ishiyama, Jun-ichi,Senda, Yasuhisa,Imaizumi, Shin
, p. 1243 - 1244 (2007/10/02)
Anomalously high selectivities on Pd and Co black catalysts were observed in the catalytic hydrogenation of 7-methylbicyclonon-6-en-3-one.Unexpected products, 1-adamantanol and 6-methylbicyclonon-6-en-3-endo-ol were exclusively produced over Pd and Co, respectively.
