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Benzothiazole, 2,2'-thiobis-, also known as 2,2'-Thiobisbenzothiazole or Thiabendazole, is an organic compound with the chemical formula C14H8N2S3. It is a white crystalline solid that is widely used as a fungicide in agriculture, particularly for the control of various plant diseases caused by fungi. The compound is also employed as a preservative in the rubber industry to prevent the growth of microorganisms that can cause degradation. Additionally, it has applications in the pharmaceutical industry and as an intermediate in the synthesis of other chemicals. Due to its broad-spectrum activity and effectiveness, 2,2'-thiobisbenzothiazole is an important chemical in the protection of crops and materials against fungal attack.

4074-77-5

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4074-77-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 4074-77-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,0,7 and 4 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 4074-77:
(6*4)+(5*0)+(4*7)+(3*4)+(2*7)+(1*7)=85
85 % 10 = 5
So 4074-77-5 is a valid CAS Registry Number.

4074-77-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name bis(2-benzothiazolyl) sulfide

1.2 Other means of identification

Product number -
Other names 2,2'-sulfanediyl-bis-benzothiazole

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:4074-77-5 SDS

4074-77-5Downstream Products

4074-77-5Relevant academic research and scientific papers

Sulfenylation of β-Diketones Using C- H Functionalization Strategy

Varun, Begur Vasanthkumar,Gadde, Karthik,Prabhu, Kandikere Ramaiah

, p. 2944 - 2947 (2015/06/30)

Sulfenylation of β-diketones is challenging as β-diketones undergo deacylation after sulfenylation in the reaction medium. The sulfenylation of β-diketones without deacylation under metal-free conditions at ambient temperature via a cross dehydrogenative coupling (CDC) strategy is reported. The resultant products can be further manipulated to form α,α-disubstituted β-diketones and pyrazoles.

Regioselective thiolation of arenes and heteroarenes: C-H functionalization strategy for C-S bond formation

Varun, Begur Vasanthkumar,Prabhu, Kandikere Ramaiah

supporting information, p. 9655 - 9668 (2015/01/16)

A facile transition-metal-free oxidative cross-dehydrogenative coupling reaction involving selective formation of a C-S bond leading to the synthesis of arylthiobenzoxazoles, heteroarylthiobenzoxazoles, and arylthiobenzothiazoles has been described. This highly regioselective C-H functionalization reaction with electron-rich aromatic systems including heteroaromatics is achieved by reversing the reactivity of sulfur in the presence of a suitable oxidant and strong acid. (Chemical Equation Presented).

Chemical Interactions between 2-Mercaptobenzazoles and ?-Acceptors

Hassan, A. A.,Mohamed, N. K.,El-Tamany, E. H.,Ali, B. A.,Mourad, A. E.

, p. 653 - 662 (2007/10/02)

2-Mercaptobenzazoles (1a-c) interact with several ?-acceptors such as tetracyanoethylene (TCNE), 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ), 2,3,5,6-tetrachloro-1,4-benzoquinone (CHL), dicyanomethyleneindane-1,3-dione (CNIND), 2,3-dicyano-1,4-naphthoquinone (DCNQ), 9-dicyanomethylene-2,4,7-trinitrofluorene (DTF), and 2,3-dichloro-1,4-naphthoquinone (DCHNQ) via the formation of charge-transfer (CT) complexes to yield various heterocyclic compounds. - Keywords: 2-Mercaptobenzazoles; Molecular interactions; ?-Acceptors

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