40764-14-5Relevant academic research and scientific papers
Thiol Acidities and Thiolate Ion Reactivities toward Butyl Chloride in Dimethyl Sulfoxide Solution. The Question of Curvature in Broensted Plots
Bordwell, Frederick G.,Hughes, David L.
, p. 3224 - 3232 (1982)
Acidities of 15 benzenethiols and 5 aliphatic thiols have been measured in dimethyl sulfoxide solution.Homohydrogen bonding of the type PhS(1-)-HSPh, which is strong for phenols in Me2SO, is absent from thiophenols.On the other hand, evidence for strong i
Use of the Broensted Relationship To Detect a Mechanistic Shift for Reaction of 2-(Methylthio)ethyl Chloride with Thiophenoxide Anions
Harris, J. Milton,Sedaghat-Herati, M. R.,McManus, Samuel P.
, p. 3893 - 3894 (2007/10/02)
The linear Broensted plot for reaction of thiophenoxide ions with 2-(methylthio)ethyl chloride in DMSO changes slope for highly deactivated thiophenoxides, thus suggesting a mechanism change.Attack of a neutral nucleophile on an anionic electrophile may b
