40838-19-5

Basic information

• Product Name: .beta.-D-erythro-Hexopyranose, 1,6-anhydro-2,3-dideoxy-4-O-(phenylmethyl)-
• Synonyms: .beta.-D-erythro-Hexopyranose, 1,6-anhydro-2,3-dideoxy-4-O-(phenylmethyl)-
• CAS NO: 40838-19-5
• Molecular Formula: C₁₃H₁₆O₃
• Molecular Weight: 220.27
• Mol File: 40838-19-5.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: .beta.-D-erythro-Hexopyranose, 1,6-anhydro-2,3-dideoxy-4-O-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: .beta.-D-erythro-Hexopyranose, 1,6-anhydro-2,3-dideoxy-4-O-(phenylmethyl)-(40838-19-5)
• EPA Substance Registry System: .beta.-D-erythro-Hexopyranose, 1,6-anhydro-2,3-dideoxy-4-O-(phenylmethyl)-(40838-19-5)

Safety Data

• Hazardous Substances Data: 40838-19-5(Hazardous Substances Data)

Upstream product

• 58871-14-0 (3-benzyloxy-3,4-dihydro-2H-pyran-2-yl)-methanol 

Relevant articles and documents

Synthesis of Carbon-Branched Sugars Involving an Unprecedented 1,5- or 1,6-Alkyl Transposition Reaction

An unusual 1,5- or 1,6-alkyl transposition along with acetalization of 3-deoxy glycals is reported. TMSOTf was used as the Lewis acid for carrying out the transformation. A plausible mechanism is proposed. The novel method provided access to 2-C-branched bicyclic acetals of various deoxy-sugar derivatives as well as 2-C-branched levoglycosan derivatives.