408535-52-4Relevant academic research and scientific papers
Stereoselective additions of chiral (E)-crotylsilanes to thionium ions: Asymmetric synthesis of homoallylic thioethers
Liu, Ping,Binnun, Eva D.,Schaus, Jennifer V.,Valentino, Nicole M.,Panek, James S.
, p. 1705 - 1707 (2007/10/03)
Stereochemically well-defined homoallylic thioethers 3 are synthesized via Lewis acid promoted condensation reaction between chiral organosilane reagents 2 and in situ generated thionium ions. The stereochemical course of the reaction is consistent with earlier reports concerning crotylsilations of oxonium ions.
