409094-19-5Relevant academic research and scientific papers
Regiospecific formation and unusual optical properties of 2,5-bis(arylethynyl)rhodacyclopentadienes: A new class of luminescent organometallics
Steffen, Andreas,Ward, Richard M.,Tay, Meng Guan,Edkins, Robert M.,Seeler, Fabian,Van Leeuwen, Magda,Beeby, Andrew,Batsanov, Andrei S.,Howard, Judith A. K.,Marder, Todd B.
, p. 3652 - 3666 (2014)
A series of 2,5-bis(arylethynyl)rhodacyclopentadienes has been prepared by a rare example of regiospecific reductive coupling of 1,4-(p-R-phenyl)-1,3- butadiynes (R=H, Me, OMe, SMe, NMe2, CF3, CO 2Me, CN, NO2, -
Regiospecific high yield reductive coupling of diynes to give a luminescent rhodium complex
Rourke,Batsanov,Howard,Marder
, p. 2626 - 2627 (2001)
Reaction of 2 equivalents of 1,4-bis(p-tolylethynyl)buta1,3-diyne with [(PMe3)4Rh(-C=CSiMe3)] gives the unusual, highly luminescent mer, cis-[tris(trimethylphosphine) trimethylsilylethynyl-2,5-bis(p-tolylethynyl)-3,4-bis(p
