409095-68-7Relevant academic research and scientific papers
Intramolecular electrophilic rearrangements in saturated acyclic systems. C→N migrations of acetyl group
Gololobov,Galkina,Dovgan',Krasnova,Petrovskii,Schmutzler,Karasar,Freitag,Jones
, p. 1061 - 1067 (2001)
Reactions between isocyanates and carbanions with an acetyl group at the carbanion center occur via rearrangement of the intermediate N-anions into isomeric C-anions by C→N-migration of the MeC(O) group. The acetyl group undergoes migration easier than the ethoxycarbonyl group. The P-zwitterionic rearrangement products were subjected to X-ray diffraction analysis.
