409096-36-2Relevant academic research and scientific papers
Structural isomers of the chromium bis(phosphoranimine)methanide complex [(HC(PPh2NSiMe3)2)Cr(μ-Cl)]2
Wei, Pingrong,Stephan, Douglas W.
, p. 1308 - 1310 (2002)
The species [(HC(PPh2NSiMe3)2Cr(μ-Cl)2] was prepared and structurally characterized. It is shown to exist in two structural isomers: one in which the Cr center adopts a pseudo-square-planar coordination geometry and another where the metal coordination sphere is better described as trigonal bipyramidal. Preliminary assessment of the catalytic activity in ethylene polymerization is also reported.
