4096-28-0Relevant articles and documents
Substrate-Selectivity in Catalytic Photooxygenation Processes Using a Quinine-BODIPY System
Coeffard, Vincent,Fischer, Jér?me,Nun, Pierrick,Serier-Brault, Hélène
supporting information, p. 463 - 468 (2020/03/13)
Substrate selectivity by means of synthetic catalysts remains a challenging topic in chemistry. Here, a catalytic system combining an iodo-BODIPY photosensitizer and quinine was evaluated in the competitive photooxygenation of non-hydrogen and hydrogen-bond-donor substrates. The ability of quinine to activate hydrogen-bond-donor substrates towards photooxygenation was reported and the results were benchmarked with photooxygenation experiments in the absence of quinine.
Studies on the Autoxidation of Some Monocyclic Olefins
Blau, K.,Mueller, U.,Pritzkow, W.,Schmidt-Renner, W.,Sedshaw, Z.
, p. 915 - 932 (2007/10/02)
The autoxidations of cyclopentene, cyclohexene, cycloheptene, cyclooctene, cycloocta-1,5-diene, 1-methylcyclopentene, 1-methylcyclohexene, 1-methylcycloheptene, 1-methylcyclooctene, methylene cyclopentene, and methylene cyclohexene with pure oxygen under normal pressure were studied.The epoxides formed were determined gaschromatographically.In most cases also the products of allylic oxidation were analyzed and their structures elucidated after reduction to the corresponding allyl alcohols.The portions of high boiling or polymeric products which could not be detected gaschromatographically and also the real yields of epoxides were determined by balance experiments in the presence of inert internal standards.
