410083-98-6Relevant academic research and scientific papers
Migratory insertion of isonitriles into titanacyclobutane complexes. A novel stereocontrolled synthesis of substituted cyclobutanimines
Greidanus-Strom, Grace,Carter, Charles A.G.,Stryker, Jeffrey M.
, p. 1011 - 1013 (2008/10/08)
Migratory insertion of isonitriles into titanacyclobutane complexes was investigated. A stereocontrolled synthesis of substituted cyclobutanimines was also studied. Using the sterically crowded permethyltitanocene system, the intermediate iminoacyl complex is isolable and can be diverted by carbonylation to yield five-membered-ring enamidolate complexes.
